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SOLAR ENERGY FACTS &
INFORMATION
The United Kingdom currently relies
heavily on coal, oil, and natural gas for
its energy. Fossil fuels are non-renewable,
that is, they draw on finite resources that
will eventually dwindle, becoming too
expensive or too environmentally damaging to
retrieve. In contrast, renewable energy
resources-such as wind and solar energy-are
constantly replenished and will never run
out.
Most renewable energy comes either
directly or indirectly from the sun.
Sunlight, or solar energy, can be used
directly for heating and lighting homes and
other buildings, for generating electricity,
and for hot water heating, solar cooling,
and a variety of commercial and industrial
uses.
The sun's heat also drives the winds,
whose energy is captured with wind turbines.
Then, the winds and the sun's heat cause
water to evaporate. When this water vapour
turns into rain or snow and flows downhill
into rivers or streams, its energy can be
captured using hydroelectric power.
Along with the rain and snow, sunlight
causes plants to grow. The organic matter
that makes up those plants is known as
biomass. Biomass can be used to produce
electricity, transportation fuels, or
chemicals. The use of biomass for any of
these purposes is called biomass energy.
Hydrogen also can be found in many organic
compounds, as well as water. It's the most
abundant element on the Earth. But it
doesn't occur naturally as a gas. It's
always combined with other elements, such as
with oxygen to make water. Once separated
from another element, hydrogen can be burned
as a fuel or converted into electricity.
Not all renewable energy resources come
from the sun. Geothermal energy taps the
Earth's internal heat for a variety of uses,
including electric power production, and the
heating and cooling of buildings. And the
energy of the ocean's tides comes from the
gravitational pull of the moon and the sun
upon the Earth.
In fact, ocean energy comes from a number
of sources. In addition to tidal energy,
there's the energy of the ocean's waves,
which are driven by both the tides and the
winds. The sun also warms the surface of the
ocean more than the ocean depths, creating a
temperature difference that can be used as
an energy source. All these forms of ocean
energy can be used to produce electricity.
re layers of different materials with
different band gaps. The higher band gap
material is on the surface, absorbing
high-energy photons while allowing
lower-energy photons to be absorbed by the
lower band gap material beneath. This
technique can result in much higher
efficiencies. Such cells, called
multi-junction cells, can have more than one
electric field.
Why is renewable energy important?
Renewable energy is important because of
the benefits it provides. The key benefits
are:
Environmental benefits -
Renewable energy technologies are clean
sources of energy that have a much lower
environmental impact than conventional
energy technologies.
Energy for our children's children's
children -
Renewable energy will not run out. Ever.
Other sources of energy are finite and will
some day be depleted.
Energy security -
After the oil supply disruptions of the
early 1970s, our nation has increased its
dependence on foreign oil supplies instead
of decreasing it. This increased dependence
impacts more than just our national energy
policy.
HOW SOLAR ENERGY IS CAPTURED FOR LIGHTING
PRODUCTS
You've probably seen calculators that
have solar cells -- calculators that never
need batteries, and in some cases don't even
have an off button. As long as you have
enough light, they seem to work forever. You
have probably also been hearing about the
"solar revolution" for the last 20 years --
the idea that one day we will all use free
electricity from the sun. This is a
seductive promise: On a bright, sunny day,
the sun shines approximately 1,000 watts of
energy per square meter of the planet's
surface, and if we could collect all of that
energy we could easily power our homes and
offices for free. But, to start with, solar
lighting for around your home and garden
makes great sense as it is so fast and easy
to install with no wires and no electricity
costs. Its safe, simple and we have many
designs to choose from. For those
technically minded or you simply want to
know more about solar energy and how it is
created then read on...
Converting Photons to Electrons -
The solar cells that you see on
calculators and satellites are photovoltaic
cells or modules (modules are simply a group
of cells electrically connected and packaged
in one frame). Photovoltaics, as the word
implies (photo = light, voltaic =
electricity), convert sunlight directly into
electricity. Once used almost exclusively in
space, photovoltaics are used more and more
in less exotic ways. They could even power
your house. How do these devices work?
Photovoltaic (PV) cells are made of
special materials called semiconductors such
as silicon, which is currently the most
commonly used. Basically, when light strikes
the cell, a certain portion of it is
absorbed within the semiconductor material.
This means that the energy of the absorbed
light is transferred to the semiconductor.
The energy knocks electrons loose, allowing
them to flow freely. PV cells also all have
one or more electric fields that act to
force electrons freed by light absorption to
flow in a certain direction. This flow of
electrons is a current, and by placing metal
contacts on the top and bottom of the PV
cell, we can draw that current off to use
externally. For example, the current can
power a calculator. This current, together
with the cell's voltage (which is a result
of its built-in electric field or fields),
defines the power (or wattage) that the
solar cell can produce.
That's the basic process, but there's
really much more to it. Let's take a deeper
look into one example of a PV cell: the
single crystal silicon cell.
Silicon in Solar Cells-
Silicon has some special chemical
properties, especially in its crystalline
form. An atom of silicon has 14 electrons,
arranged in three different shells. The
first two shells, those closest to the
centre, are completely full. The outer
shell, however, is only half full, having
only four electrons. A silicon atom will
always look for ways to fill up its last
shell (which would like to have eight
electrons). To do this, it will share
electrons with four of its neighbour silicon
atoms. It's like every atom holds hands with
its neighbours, except that in this case,
each atom has four hands joined to four
neighbours. That's what forms the crystalline
structure, and that structure turns out to
be important to this type of PV cell.
We've now described pure, crystalline
silicon. Pure silicon is a poor conductor of
electricity because none of its electrons
are free to move about, as electrons are in
good conductors such as copper. Instead, the
electrons are all locked in the crystalline
structure. The silicon in a solar cell is
modified slightly so that it will work as a
solar cell.
Our cell has silicon with impurities --
other atoms mixed in with the silicon atoms,
changing the way things work a bit. We
usually think of impurities as something
undesirable, but in our case, our cell
wouldn't work without them. These impurities
are actually put there on purpose. Consider
silicon with an atom of phosphorous here and
there, maybe one for every million silicon
atoms. Phosphorous has five electrons in its
outer shell, not four. It still bonds with
its silicon neighbour atoms, but in a sense,
the phosphorous has one electron that
doesn't have anyone to hold hands with. It
doesn't form part of a bond, but there is a
positive proton in the phosphorous nucleus
holding it in place.
When energy is added to pure silicon, for
example in the form of heat, it can cause a
few electrons to break free of their bonds
and leave their atoms. A hole is left behind
in each case. These electrons then wander
randomly around the crystalline lattice
looking for another hole to fall into. These
electrons are called free carriers, and can
carry electrical current. There are so few
of them in pure silicon, however, that they
aren't very useful. Our impure silicon with
phosphorous atoms mixed in is a different
story. It turns out that it takes a lot less
energy to knock loose one of our "extra"
phosphorous electrons because they aren't
tied up in a bond -- their neighbours aren't
holding them back. As a result, most of
these electrons do break free, and we have a
lot more free carriers than we would have in
pure silicon. The process of adding
impurities on purpose is called doping, and
when doped with phosphorous, the resulting
silicon is called N-type ("n" for negative)
because of the prevalence of free electrons.
N-type doped silicon is a much better
conductor than pure silicon is.
Actually, only part of our cell is N-type.
The other part is doped with boron, which
has only three electrons in its outer shell
instead of four, to become P-type silicon.
Instead of having free electrons, P-type
silicon ("p" for positive) has free holes.
Holes really are just the absence of
electrons, so they carry the opposite
(positive) charge. They move around just
like electrons do.
So where has all this gotten us? The
interesting part starts when you put N-type
silicon together with P-type silicon.
Remember that every PV cell has at least one
electric field. Without an electric field,
the cell wouldn't work, and this field forms
when the N-type and P-type silicon are in
contact. Suddenly, the free electrons in the
N side, which have been looking all over for
holes to fall into, see all the free holes
on the P side, and there's a mad rush to
fill them in.
Before now, our silicon was all
electrically neutral. Our extra electrons
were balanced out by the extra protons in
the phosphorous. Our missing electrons
(holes) were balanced out by the missing
protons in the boron. When the holes and
electrons mix at the junction between N-type
and P-type silicon, however, that neutrality
is disrupted. Do all the free electrons fill
all the free holes? No. If they did, then
the whole arrangement wouldn't be very
useful. Right at the junction, however, they
do mix and form a barrier, making it harder
and harder for electrons on the N side to
cross to the P side. Eventually, equilibrium
is reached, and we have an electric field
separating the two sides.
This electric field acts as a diode,
allowing (and even pushing) electrons to
flow from the P side to the N side, but not
the other way around. It's like a hill --
electrons can easily go down the hill (to
the N side), but can't climb it (to the P
side).
So we've got an electric field acting as a
diode in which electrons can only move in
one direction. Let's see what happens when
light hits the cell.
When Light Hits the Cell -
When light, in the form of photons, hits
our solar cell, its energy frees
electron-hole pairs.
Each photon with enough energy will
normally free exactly one electron, and
result in a free hole as well. If this
happens close enough to the electric field,
or if free electron and free hole happen to
wander into its range of influence, the
field will send the electron to the N side
and the hole to the P side. This causes
further disruption of electrical neutrality,
and if we provide an external current path,
electrons will flow through the path to
their original side (the P side) to unite
with holes that the electric field sent
there, doing work for us along the way. The
electron flow provides the current, and the
cell's electric field causes a voltage. With
both current and voltage, we have power,
which is the product of the two.
How much sunlight energy does our PV cell
absorb? Unfortunately, the most that our
simple cell could absorb is around 25
percent, and more likely is 15 percent or
less. Why so little?
Energy Loss -
Why does our solar cell absorb only about
15 percents of the sunlight's energy?
Visible light is only part of the
electromagnetic spectrum. Electromagnetic
radiation is not monochromatic, it is made
up of a range of different wavelengths, and
therefore energy levels.
Light can be separated into different
wavelengths, and we can see them in the form
of a rainbow. Since the light that hits our
cell has photons of a wide range of
energies, it turns out that some of them
won't have enough energy to form an
electron-hole pair. They'll simply pass
through the cell as if it were transparent.
Still other photons have too much energy.
Only a certain amount of energy, measured in
electron volts (eV) and defined by our cell
material (about 1.1 eV for crystalline
silicon), is required to knock an electron
loose. We call this the band gap energy of a
material. If a photon has more energy than
the required amount, then the extra energy
is lost (unless a photon has twice the
required energy, and can create more than
one electron-hole pair, but this effect is
not significant). These two effects alone
account for the loss of around 70 percent of
the radiation energy incident on our cell.
Why can't we choose a material with a
really low band gap, so we can use more of
the photons? Unfortunately, our band gap
also determines the strength (voltage) of
our electric field, and if it's too low,
then what we make up in extra current (by
absorbing more photons), we lose by having a
small voltage. Remember that power is
voltage times current. The optimal band gap,
balancing these two effects, is around 1.4
eV for a cell made from a single material.
We have other losses as well. Our
electrons have to flow from one side of the
cell to the other through an external
circuit. We can cover the bottom with a
metal, allowing for good conduction, but if
we completely cover the top, then photons
can't get through the opaque conductor and
we lose all of our current (in some cells,
transparent conductors are used on the top
surface, but not in all). If we put our
contacts only at the sides of our cell, then
the electrons have to travel an extremely
long distance (for an electron) to reach the
contacts. Remember, silicon is a
semiconductor -- it's not nearly as good as
a metal for transporting current. Its
internal resistance (called series
resistance) is fairly high, and high
resistance means high losses. To minimize
these losses, our cell is covered by a
metallic contact grid that shortens the
distance that electrons have to travel while
covering only a small part of the cell
surface. Even so, some photons are blocked
by the grid, which can't be too small or
else its own resistance will be too high.
Finishing the Cell
There are a few more steps left before we
can really use our cell. Silicon happens to
be a very shiny material, which means that
it is very reflective. Photons that are
reflected can't be used by the cell. For
that reason, an antireflective coating is
applied to the top of the cell to reduce
reflection losses to less than 5 percent.
The final step is the glass or plastic
cover plate that protects the cell from the
elements. PV modules are made by connecting
several cells (usually 36) in series and
parallel to achieve useful levels of voltage
and current, and putting them in a sturdy
frame complete with a glass cover and
positive and negative terminals on the back. |